Singlet state formation and its impact on the magnetic structure in the tetramer system SeCuO3
We present an experimental investigation of the magnetic structure in a tetramer system SeCuO3 using neutron powder-diffraction and nuclear resonance techniques. We establish a commensurate antiferromagnetic ordering with a propagation vector k = (0, 0, 1). The order parameter follows a critical behavior near T-N = 8 K with a critical exponent beta = 0.32 in agreement with a three-dimensional universality class. Evidence is presented that a singlet state starts to form on tetramers at temperatures as high as 200 K, and its signature is preserved within the ordered state through a strong renormalization of the ordered magnetic moment on two nonequivalent copper sites m(Cu1) approximate to 0.35(mu B) and m(Cu2) < 0.8(mu B) at 1.5 K.
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Cvitanić, T., Šurija, V., Prša, K., Zaharko, O., Kupčić, I., Babkevich, P., Frontzek, M., Požek, M., Berger, H., Magrez, A., Rønnow, H. M., Grbić, M. S., & Živković, I. (2018). Singlet state formation and its impact on the magnetic structure in the tetramer system SeCuO3. Physical Review B, 98(5), Article 054409. https://doi.org/10.1103/PhysRevB.98.054409
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2018
98
5
054409
REVIEWED
EPFL
| Funder | Grant Number |
FNS | 166298 |
FNS | 169699 |