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  4. Singlet state formation and its impact on the magnetic structure in the tetramer system SeCuO3
 
research article

Singlet state formation and its impact on the magnetic structure in the tetramer system SeCuO3

Cvitanić, Tonči
•
Šurija, Vinko
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Prša, Krunoslav
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2018
Physical Review B

We present an experimental investigation of the magnetic structure in a tetramer system SeCuO3 using neutron powder-diffraction and nuclear resonance techniques. We establish a commensurate antiferromagnetic ordering with a propagation vector k = (0, 0, 1). The order parameter follows a critical behavior near T-N = 8 K with a critical exponent beta = 0.32 in agreement with a three-dimensional universality class. Evidence is presented that a singlet state starts to form on tetramers at temperatures as high as 200 K, and its signature is preserved within the ordered state through a strong renormalization of the ordered magnetic moment on two nonequivalent copper sites m(Cu1) approximate to 0.35(mu B) and m(Cu2) < 0.8(mu B) at 1.5 K.

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