Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Phase changes and amorphization of zeolites at high pressures: The case of scolecite and mesolite
 
research article

Phase changes and amorphization of zeolites at high pressures: The case of scolecite and mesolite

Malezieux, J.M.
•
Itie, J.P.
•
Gillet, P.  
1996
American Mineralogist

Pressure-induced amorphous-phase transitions (amorphization) have been observed in framework silicates like quartz and feldspars. A similar crystalline to highly disordered solid phase transition is reported in this study for two zeolites, scolecite and mesolite. Pressure-induced amorphization is demonstrated using in situ X-ray diffraction and Raman spectroscopy. Before complete amorphization, progressive structural changes are observed below 10 GPa. The transition from the crystal to the amorphous phase is irreversible, and the pressure-quenched samples exhibit Raman spectra that bear strong resemblance to aluminosilicate glasses obtained by quenching a liquid. In some cases, however, decompression from 15 GPa of fully amorphized samples is accompanied by a rim recrystallization of the sample and preservation of an amorphous phase with a structure different from that quenched in other experiments. Shear stresses seem to have important control of the transformation occurring during the decompression of the samples.

  • Details
  • Metrics
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés