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  4. Phase changes and amorphization of zeolites at high pressures: The case of scolecite and mesolite
 
research article

Phase changes and amorphization of zeolites at high pressures: The case of scolecite and mesolite

Malezieux, J.M.
•
Itie, J.P.
•
Gillet, P.  
1996
American Mineralogist

Pressure-induced amorphous-phase transitions (amorphization) have been observed in framework silicates like quartz and feldspars. A similar crystalline to highly disordered solid phase transition is reported in this study for two zeolites, scolecite and mesolite. Pressure-induced amorphization is demonstrated using in situ X-ray diffraction and Raman spectroscopy. Before complete amorphization, progressive structural changes are observed below 10 GPa. The transition from the crystal to the amorphous phase is irreversible, and the pressure-quenched samples exhibit Raman spectra that bear strong resemblance to aluminosilicate glasses obtained by quenching a liquid. In some cases, however, decompression from 15 GPa of fully amorphized samples is accompanied by a rim recrystallization of the sample and preservation of an amorphous phase with a structure different from that quenched in other experiments. Shear stresses seem to have important control of the transformation occurring during the decompression of the samples.

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Type
research article
DOI
10.2138/am-1996-5-612
Web of Science ID

WOS:A1996UP41100012

Author(s)
Malezieux, J.M.
Itie, J.P.
Gillet, P.  
Date Issued

1996

Published in
American Mineralogist
Volume

81

Issue

5-6

Start page

651

End page

657

Subjects

Alpha-Quartz

•

Silica

•

Framework

•

Glasses

•

Solids

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
EPSL  
Available on Infoscience
September 29, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/71303
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