research article
Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand
June 10, 2024
Carbodicarbenes are strong C‐donor ligands, which have found numerous applications in organometallic and main group element chemistry. Herein, we report a structurally distinct carbodicarbene ligand, which is formed by dinitrogenative coupling of a Fischer carbene complex with an N‐heterocyclic diazoolefin. The resulting carbonyl complex serves as a stable source for the mixed Arduengo‐Fischer carbodicarbene ligand. Facile ligand transfer reactions were demonstrated to occur with gold(I), copper(I), palladium(II), and rhodium(I) complexes.
Type
research article
Author(s)
Date Issued
2024-06-10
Publisher
Published in
Editorial or Peer reviewed
REVIEWED
Written at
EPFL
EPFL units
| Funder | Grant Number |
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung | |
Available on Infoscience
August 2, 2024
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