Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand
 
research article

Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand

Kooij, Bastiaan  
•
Chen, Damien Wen  
•
Fadaei Tirani, Farzaneh  
Show more
June 10, 2024
Angewandte Chemie International Edition

Carbodicarbenes are strong C‐donor ligands, which have found numerous applications in organometallic and main group element chemistry. Herein, we report a structurally distinct carbodicarbene ligand, which is formed by dinitrogenative coupling of a Fischer carbene complex with an N‐heterocyclic diazoolefin. The resulting carbonyl complex serves as a stable source for the mixed Arduengo‐Fischer carbodicarbene ligand. Facile ligand transfer reactions were demonstrated to occur with gold(I), copper(I), palladium(II), and rhodium(I) complexes.

  • Files
  • Details
  • Metrics
Type
research article
DOI
10.1002/anie.202407945
Author(s)
Kooij, Bastiaan  
Chen, Damien Wen  

EPFL

Fadaei Tirani, Farzaneh  
Severin, Kay  

EPFL

Date Issued

2024-06-10

Publisher

Wiley

Published in
Angewandte Chemie International Edition
Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCS  
FunderGrant Number

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Available on Infoscience
August 2, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/240542
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés