Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand
Carbodicarbenes are strong C‐donor ligands, which have found numerous applications in organometallic and main group element chemistry. Herein, we report a structurally distinct carbodicarbene ligand, which is formed by dinitrogenative coupling of a Fischer carbene complex with an N‐heterocyclic diazoolefin. The resulting carbonyl complex serves as a stable source for the mixed Arduengo‐Fischer carbodicarbene ligand. Facile ligand transfer reactions were demonstrated to occur with gold(I), copper(I), palladium(II), and rhodium(I) complexes.
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Kooij, B., Chen, D. W., Fadaei Tirani, F., & Severin, K. (2024). Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202407945
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Angew Chem Int Ed - 2024 - Kooij - Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand.pdf
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