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research article

Interactions between aluminium and fired passivating contacts during fire-through metallization

Libraro, S.  
•
Lehmann, M.  
•
Leon, J. J. Diaz
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January 1, 2023
Solar Energy Materials And Solar Cells

Replacing silver metallization with earth-abundant materials in Si solar cells is a critical step towards the sustainable growth of photovoltaics. In this work, we investigate fire-through processes using Al for the metallization of solar cells with p-type passivating contacts, with the goal to achieve a thin depth of contact, oppositely to what is used for standard back-surface field Al contacts. The interactions taking place during firing between the different elements in our contact stack (Al, SiNx:H, SiCx(p) and tunnel SiOx) are studied. We discuss how Al and SiNx react during firing by performing contact formation through different nitride layers, and show that increasing the N content of the silicon nitride can reduce Al penetration depth. Finally, we also investigate the mechanisms behind metal-induced passivation degradation and identify possible ways of mitigating them by employing an adapted SiOx/SiCx stack to allow for Ag-free metallization of tunnel oxide passivating contacts.

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Type
research article
DOI
10.1016/j.solmat.2022.112051
Web of Science ID

WOS:000877796600006

Author(s)
Libraro, S.  
Lehmann, M.  
Leon, J. J. Diaz
Allebe, C.
Descoeudres, A.
Ingenito, A.
Ballif, C.  
Hessler-Wyser, A.  
Haug, F-J  
Date Issued

2023-01-01

Publisher

ELSEVIER

Published in
Solar Energy Materials And Solar Cells
Volume

249

Article Number

112051

Subjects

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Physics, Applied

•

Energy & Fuels

•

Materials Science

•

Physics

•

solar-cells

•

film

•

resistance

•

emitters

•

glass

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

Available on Infoscience
January 16, 2023
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/193728
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