Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Analysis of Complex Spectra Using Fourier Filtering
 
research article

Analysis of Complex Spectra Using Fourier Filtering

de Beer, Alex G. F.
•
Scheu, Rüdiger  
•
Chen, Yixing  
Show more
2013
Journal Of Physical Chemistry C

We present a method to analyze complex spectral data, such as that obtained from vibrational sumfrequency generation (SFG), using Fourier filtering. The proposed filter locates the center frequency of all resonances in a complex data set. The analysis is useful for spectral data that consist of multiple overlapping peaks or with sharp resonances that interfere with a broad background, in which locating resonances is of high interest to characterize spectra, but usually difficult to implement. We apply the filter to complex spectra obtained from maximum entropy analysis of both numerically generated SFG intensity data containing multiple resonances from known line-shape parameters and experimental SFG intensity data from the quartz/OTS/water interface. By having an unambiguous determination of the resonance frequencies, spectral analysis can be improved. The method also provides an easy check for validating interferometric measurements. Although the method is here applied to SFG data, it can be used with any type of complex spectral data (such as CARS) and is useful to eliminate the effects of a large nonresonant background.

  • Details
  • Metrics
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés