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research article

Analysis of Complex Spectra Using Fourier Filtering

de Beer, Alex G. F.
•
Scheu, Rüdiger  
•
Chen, Yixing  
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2013
Journal Of Physical Chemistry C

We present a method to analyze complex spectral data, such as that obtained from vibrational sumfrequency generation (SFG), using Fourier filtering. The proposed filter locates the center frequency of all resonances in a complex data set. The analysis is useful for spectral data that consist of multiple overlapping peaks or with sharp resonances that interfere with a broad background, in which locating resonances is of high interest to characterize spectra, but usually difficult to implement. We apply the filter to complex spectra obtained from maximum entropy analysis of both numerically generated SFG intensity data containing multiple resonances from known line-shape parameters and experimental SFG intensity data from the quartz/OTS/water interface. By having an unambiguous determination of the resonance frequencies, spectral analysis can be improved. The method also provides an easy check for validating interferometric measurements. Although the method is here applied to SFG data, it can be used with any type of complex spectral data (such as CARS) and is useful to eliminate the effects of a large nonresonant background.

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Type
research article
DOI
10.1021/jp406161n
Author(s)
de Beer, Alex G. F.
Scheu, Rüdiger  
Chen, Yixing  
Conboy, John C.
Roke, Sylvie  
Date Issued

2013

Publisher

Amer Chemical Soc

Published in
Journal Of Physical Chemistry C
Volume

117

Issue

50

Start page

26582

End page

26587

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LBP  
Available on Infoscience
January 23, 2014
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/100140
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