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research article
Isolation of a highly persistent diphosphanyl radical: the phosphorus analogue of a hydrazyl
Herein is reported the synthesis and characterization of a [RR1P-PR]-type radical, (I) (R = 2,4,6-tBu3C6H2; R' = CH3). I is stable in the solid state at temps. below -30 Deg. Suitable crystals of I were unobtainable, but a combination of EPR expts. and theor. methods allowed for unambiguous detn. of its structure. [on SciFinder (R)]
Type
research article
Authors
Loss, Sandra
•
Magistrato, Alessandra
•
Cataldo, Laurent
•
Hoffmann, Stefan
•
Geoffroy, Michel
•
•
Grutzmacher, Hansjorg
Publication date
2001
Published in
Volume
40
Issue
4
Start page
723
End page
726
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
February 27, 2006
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