research article
Isolation of a highly persistent diphosphanyl radical: the phosphorus analogue of a hydrazyl
Herein is reported the synthesis and characterization of a [RR1P-PR]-type radical, (I) (R = 2,4,6-tBu3C6H2; R' = CH3). I is stable in the solid state at temps. below -30 Deg. Suitable crystals of I were unobtainable, but a combination of EPR expts. and theor. methods allowed for unambiguous detn. of its structure. [on SciFinder (R)]
Type
research article
Author(s)
Loss, Sandra
Magistrato, Alessandra
Cataldo, Laurent
Hoffmann, Stefan
Geoffroy, Michel
Grutzmacher, Hansjorg
Date Issued
2001
Publisher
Published in
Volume
40
Issue
4
Start page
723
End page
726
Editorial or Peer reviewed
REVIEWED
Written at
EPFL
EPFL units
Available on Infoscience
February 27, 2006
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