Isolation of a highly persistent diphosphanyl radical: the phosphorus analogue of a hydrazyl
Loss, Sandra; Magistrato, Alessandra; Cataldo, Laurent; Hoffmann, Stefan; Geoffroy, Michel; Rothlisberger, Ursula; Grutzmacher, Hansjorg
2001

Abstract

Herein is reported the synthesis and characterization of a [RR1P-PR]-type radical, (I) (R = 2,4,6-tBu3C6H2; R' = CH3). I is stable in the solid state at temps. below -30 Deg. Suitable crystals of I were unobtainable, but a combination of EPR expts. and theor. methods allowed for unambiguous detn. of its structure. [on SciFinder (R)]

Details

Title Isolation of a highly persistent diphosphanyl radical: the phosphorus analogue of a hydrazyl
Author(s) Loss, Sandra ; Magistrato, Alessandra ; Cataldo, Laurent ; Hoffmann, Stefan ; Geoffroy, Michel ; Rothlisberger, Ursula ; Grutzmacher, Hansjorg
Published in Angewandte Chemie, International Edition
Volume 40
Issue 4
Pages 723-726
Date 2001
DOI https://doi.org/10.1002/1521-3773(20010216)40:4%3C723::AID-ANIE7230%3E3.0.CO;2-8
Laboratories LCBC
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCBC - Laboratory of Computational Chemistry and Biochemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Record creation date 2006-02-27

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