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research article

Doping and phase segregation in Mn2+- and Co2+-doped lead halide perovskites from Cs-133 and H-1 NMR relaxation enhancement

Kubicki, Dominik J.  
•
Prochowicz, Daniel  
•
Pinon, Arthur  
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February 7, 2019
Journal of Materials Chemistry A

Lead halide perovskites belong to a broad class of compounds with appealing optoelectronic and photovoltaic properties. Doping with transition metal ions such as Mn2+ and Co2+ has recently been reported to substantially enhance luminescence and stability of these materials. However, so far atomic-level evidence for incorporation of the dopants into perovskite phases has been missing. Here, we introduce a general and straightforward method for confirming the substitutional doping of bulk perovskite phases with paramagnetic dopants. Using Cs-133 and H-1 solid-state MAS NMR relaxation measurements we provide for the first time direct evidence that, consistent with current understanding, Mn2+ is incorporated into the perovskite lattice of CsPbCl3 and CsPbBr3 and does not form clusters. We also show that, contrary to current conviction, Co2+ is not incorporated into the perovskite lattice of MAPbI(3).

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Doping and phase segregation in Mn2+- and Co2+-doped lead halide perovskites from 133Cs and 1H NMR relaxation enhancement .pdf

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