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  4. Doping and phase segregation in Mn2+- and Co2+-doped lead halide perovskites from Cs-133 and H-1 NMR relaxation enhancement
 
research article

Doping and phase segregation in Mn2+- and Co2+-doped lead halide perovskites from Cs-133 and H-1 NMR relaxation enhancement

Kubicki, Dominik J.  
•
Prochowicz, Daniel  
•
Pinon, Arthur  
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February 7, 2019
Journal of Materials Chemistry A

Lead halide perovskites belong to a broad class of compounds with appealing optoelectronic and photovoltaic properties. Doping with transition metal ions such as Mn2+ and Co2+ has recently been reported to substantially enhance luminescence and stability of these materials. However, so far atomic-level evidence for incorporation of the dopants into perovskite phases has been missing. Here, we introduce a general and straightforward method for confirming the substitutional doping of bulk perovskite phases with paramagnetic dopants. Using Cs-133 and H-1 solid-state MAS NMR relaxation measurements we provide for the first time direct evidence that, consistent with current understanding, Mn2+ is incorporated into the perovskite lattice of CsPbCl3 and CsPbBr3 and does not form clusters. We also show that, contrary to current conviction, Co2+ is not incorporated into the perovskite lattice of MAPbI(3).

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Type
research article
DOI
10.1039/c8ta11457a
Web of Science ID

WOS:000457546000040

Author(s)
Kubicki, Dominik J.  
Prochowicz, Daniel  
Pinon, Arthur  
Stevanato, Gabriele  
Hofstetter, Albert  
Zakeeruddin, Shaik M.  
Gratzel, Michael  
Emsley, Lyndon  
Date Issued

2019-02-07

Publisher

Royal Society of Chemistry

Published in
Journal of Materials Chemistry A
Volume

7

Issue

5

Start page

2326

End page

2333

Subjects

Chemistry, Physical

•

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Chemistry

•

Energy & Fuels

•

Materials Science

•

spin-lattice-relaxation

•

solid-state nmr

•

hybrid perovskites

•

energy-transfer

•

quantum dots

•

anion-exchange

•

nanocrystals

•

dynamics

•

spectroscopy

•

substitution

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
LRM  
Available on Infoscience
February 15, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/154483
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