A molecularly engineered hole-​transporting material for efficient perovskite solar cells

Soln.-​processable perovskite solar cells have recently achieved certified power conversion efficiencies of over 20​%, challenging the long-​standing perception that high efficiencies must come at high costs. One major bottleneck for increasing the efficiency even further is the lack of suitable hole-​transporting materials, which ext. pos. charges from the active light absorber and transmit them to the electrode. In this work, we present a molecularly engineered hole-​transport material with a simple dissym. fluorene-​dithiophene (FDT) core substituted by N,​N-​di-​p-​methoxyphenylamine donor groups, which can be easily modified, providing the blueprint for a family of potentially low-​cost hole-​transport materials. We use FDT on state-​of-​the-​art devices and achieve power conversion efficiencies of 20.2​% which compare favorably with control devices with 2,​2',​7,​7'-​tetrakis(N,​N-​di-​p-​methoxyphenylamine)​-​9,​9'-​spirobifluorene (spiro-​OMeTAD)​. Thus, this new hole transporter has the potential to replace spiro-​OMeTAD.


Published in:
Nature Energy, 1, 2, 15017
Year:
2016
Publisher:
London, Nature Publishing Group
Note:
Nature Energy Volume1 Issue2 Pages15017 Journal; Online Computer File 2016 CODEN:NEANFD ISSN:2058-7546 DOI:10.1038/nenergy.2015.17
Laboratories:




 Record created 2017-03-11, last modified 2018-12-03


Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)