Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal-Organic Frameworks
2012
Abstract
A matter of minutes: Dynamic nuclear polarization (DNP) is applied to enhance the signal of solid-state NMR spectra of metal-organic framework (MOF) materials. The signal enhancement enables the acquisition of high-quality 1D 13C solid-state NMR spectra, 2D 1H- 13C dipolar HETCOR and 1D 15N solid-state NMR spectra with natural isotopic abundance in experiment times on the order of minutes. MW=microwaves. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Details
Title
Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal-Organic Frameworks
Author(s)
Rossini, Aaron J. ; Zagdoun, Alexandre ; Lelli, Moreno ; Canivet, Jerome ; Aguado, Sonia ; Ouari, Olivier ; Tordo, Paul ; Rosay, Melanie ; Maas, Werner E. ; Coperet, Christophe ; Farrusseng, David ; Emsley, Lyndon ; Lesage, Anne
Published in
Angewandte Chemie-International Edition
Volume
51
Issue
1
Pages
123-127
Date
2012
Publisher
WILEY-BLACKWELL
ISSN
1433-7851
Keywords
Other identifier(s)
View record in Web of Science
Laboratories
LRM
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LRM - Laboratory of Magnetic Resonance
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2015-01-08