Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal-Organic Frameworks
Rossini, Aaron J.; Zagdoun, Alexandre; Lelli, Moreno; Canivet, Jerome; Aguado, Sonia; Ouari, Olivier; Tordo, Paul; Rosay, Melanie; Maas, Werner E.; Coperet, Christophe; Farrusseng, David; Emsley, Lyndon; Lesage, Anne
2012

Abstract

A matter of minutes: Dynamic nuclear polarization (DNP) is applied to enhance the signal of solid-state NMR spectra of metal-organic framework (MOF) materials. The signal enhancement enables the acquisition of high-quality 1D 13C solid-state NMR spectra, 2D 1H- 13C dipolar HETCOR and 1D 15N solid-state NMR spectra with natural isotopic abundance in experiment times on the order of minutes. MW=microwaves. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Details

Title Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal-Organic Frameworks
Author(s) Rossini, Aaron J. ; Zagdoun, Alexandre ; Lelli, Moreno ; Canivet, Jerome ; Aguado, Sonia ; Ouari, Olivier ; Tordo, Paul ; Rosay, Melanie ; Maas, Werner E. ; Coperet, Christophe ; Farrusseng, David ; Emsley, Lyndon ; Lesage, Anne
Published in Angewandte Chemie-International Edition
Volume 51
Issue 1
Pages 123-127
Date 2012
Publisher WILEY-BLACKWELL
ISSN 1433-7851
Keywords
DOI https://doi.org/10.1002/anie.201106030
Other identifier(s) View record in Web of Science
Laboratories LRM
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LRM - Laboratory of Magnetic Resonance
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date 2015-01-08

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