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research article
Relative carbanion basicities as driving force for an intramolecular silyl migration of lithiated biphenyls
2007
A solvent-dependent silyl migration of lithiated biphenyls is described, involving the intermediate formation of a pentacoordinated silicate complex. Differences in the relative basicities of the aryllithium intermediates are the possible driving force for this migration. (c) 2007 Elsevier Ltd. All rights reserved.
Type
research article
Web of Science ID
WOS:000252097400044
Authors
Publication date
2007
Published in
Volume
48
Start page
8768
End page
8772
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
July 4, 2012
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