research article
Relative carbanion basicities as driving force for an intramolecular silyl migration of lithiated biphenyls
2007
A solvent-dependent silyl migration of lithiated biphenyls is described, involving the intermediate formation of a pentacoordinated silicate complex. Differences in the relative basicities of the aryllithium intermediates are the possible driving force for this migration. (c) 2007 Elsevier Ltd. All rights reserved.
Type
research article
Web of Science ID
WOS:000252097400044
Author(s)
Date Issued
2007
Publisher
Published in
Volume
48
Start page
8768
End page
8772
Subjects
Editorial or Peer reviewed
REVIEWED
Written at
EPFL
EPFL units
Available on Infoscience
July 4, 2012
Use this identifier to reference this record