Palladium-catalyzed arylative ring-opening reactions of norbornenols: entry to highly substituted cyclohexenes, quinolines, and tetrahydroquinolines
2010
Abstract
Palladium-catalyzed stereoselective arylative ring-opening reaction of norbornenol derivs. was studied. In presence of aryl bromides, corresponding cyclohexene derivs. were obtained in good yields. Meanwhile, reaction with bromoanilines yielded quinolines and tetrahydroquinolines. The asym. version of this reaction was explored by using chiral ligand.
Details
Title
Palladium-catalyzed arylative ring-opening reactions of norbornenols: entry to highly substituted cyclohexenes, quinolines, and tetrahydroquinolines
Author(s)
Waibel, Michael ; Cramer, Nicolai
Published in
Angewandte Chemie, International Edition
Volume
49
Pages
4455-4458
Date
2010
Publisher
Wiley-VCH Verlag GmbH & Co. KGaA
ISSN
1433-7851
Keywords
Note
CAPLUS AN 2010:758486(Journal)
Laboratories
LCSA
Record Appears in
Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > LCSA - Laboratory of Asymmetric Catalysis and Synthesis
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Peer-reviewed publications
Work outside EPFL
Journal Articles
Published
Record creation date
2011-08-17