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Temperature dependence in the multiphoton dissociation of sulfur-32 hexafluoride

The multiphoton dissocn. of 32SF6 at 10.59 mm was studied as a function of temp. between 223 and 413 K. The obsd. decrease of the reaction yield with increasing temp. varied strongly with the laser energy fluence at the applied conditions. Rate consts. for the unimol. decompn. of SF6 induced by the monochromatic IR radiation were calcd. at 223, 293, and 343 K.

    Keywords: 21110-12-3 Role: USES (Uses) (multiphoton laser dissocn. of ; temp. dependence in and rate consts. for) ; multiphoton dissocn sulfur fluoride

    Note:

    Copyright 2003 ACS

    CAPLUS

    AN 1979:499846

    CAN 91:99846

    74-1

    Radiation Chemistry, Photochemistry, and Photographic Processes

    73

    Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:

    Journal

    JCPSA6

    written in English.

    Kinetics of photolysis (of sulfur fluoride by IR laser); Photon (processes of many, in dissocn. of sulfur hexafluoride); Ionization (laser-induced, of sulfur hexafluoride); Photolysis (multiphoton, of sulfur hexafluoride, by IR laser)

    Reference

    • EPFL-ARTICLE-162784

    Record created on 2011-02-01, modified on 2016-08-09

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