Temperature dependence in the multiphoton dissociation of sulfur-32 hexafluoride
The multiphoton dissocn. of 32SF6 at 10.59 mm was studied as a function of temp. between 223 and 413 K. The obsd. decrease of the reaction yield with increasing temp. varied strongly with the laser energy fluence at the applied conditions. Rate consts. for the unimol. decompn. of SF6 induced by the monochromatic IR radiation were calcd. at 223, 293, and 343 K.
1979
70
12
5672
5675
Copyright 2003 ACS
CAPLUS
AN 1979:499846
CAN 91:99846
74-1
Radiation Chemistry, Photochemistry, and Photographic Processes
73
Inst. Chim. Phys.,Ec. Polytech. Fed.,Lausanne,Switz. FIELD URL:
Journal
JCPSA6
written in English.
Kinetics of photolysis (of sulfur fluoride by IR laser); Photon (processes of many, in dissocn. of sulfur hexafluoride); Ionization (laser-induced, of sulfur hexafluoride); Photolysis (multiphoton, of sulfur hexafluoride, by IR laser)
REVIEWED
EPFL