Wilkinson's Catalyst Catalyzed Selective Hydrogenation of Olefin in the Presence of an Aromatic Nitro Function: A Remarkable Solvent Effect

Optimal conditions for chlorotris(triphenylphosphine)rhodium(I) (Wilkinson's catalyst) catalyzed selective satn. of a double bond in the presence of a nitro function are developed. Aryl iodide and benzyl ether are also tolerated under these hydrogenation conditions. [on SciFinder (R)]


Published in:
Journal of Organic Chemistry, 67, 9, 3163-3164
Year:
2002
Keywords:
Note:
CAN 137:5940
25-1
Benzene, Its Derivatives, and Condensed Benzenoid Compounds
CNRS, Institut de Chimie des Substances Naturelles,Gif-sur-Yvette,Fr.
Journal
0022-3263
written in English.
14694-95-2 (Wilkinson's catalyst) Role: CAT (Catalyst use), USES (Uses) (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst); 4003-94-5; 39228-29-0; 114164-92-0; 130489-97-3; 433288-93-8; 433288-95-0; 433288-98-3; 433289-00-0; 433289-01-1; 433289-02-2; 433289-03-3 Role: RCT (Reactant), RACT (Reactant or reagent) (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst); 433289-12-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst); 1664-65-9P; 14310-29-3P; 20716-26-1P; 433289-04-4P; 433289-05-5P; 433289-06-6P; 433289-07-7P; 433289-08-8P; 433289-09-9P; 433289-10-2P; 433289-11-3P Role: SPN (Synthetic preparation), PREP (Preparation) (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst)
Laboratories:




 Record created 2010-11-25, last modified 2018-09-13


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