research article

Wilkinson's Catalyst Catalyzed Selective Hydrogenation of Olefin in the Presence of an Aromatic Nitro Function: A Remarkable Solvent Effect

Jourdant, Angelique
•
Gonzalez-Zamora, Eduardo
•
Zhu, Jieping  
2002
The Journal of Organic Chemistry

Optimal conditions for chlorotris(triphenylphosphine)rhodium(I) (Wilkinson's catalyst) catalyzed selective satn. of a double bond in the presence of a nitro function are developed. Aryl iodide and benzyl ether are also tolerated under these hydrogenation conditions. [on SciFinder (R)]

Type
research article
DOI
10.1021/jo025595q
Author(s)
Jourdant, Angelique
Gonzalez-Zamora, Eduardo
Zhu, Jieping  
Date Issued

2002

Published in
The Journal of Organic Chemistry
Volume

67

Issue

9

Start page

3163

End page

3164

Subjects

Hydrogenation; Hydrogenation catalysts (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst); Nitro compounds Role: MSC (Miscellaneous) (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst); Alkenes Role: RCT (Reactant)

•

RACT (Reactant or reagent) (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst); Solvent effect (on hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst)

•

hydrogenation olefin nitro function Wilkinsons catalyst

Note

CAN 137:5940

25-1

Benzene, Its Derivatives, and Condensed Benzenoid Compounds

CNRS, Institut de Chimie des Substances Naturelles,Gif-sur-Yvette,Fr.

Journal

written in English.

14694-95-2 (Wilkinson's catalyst) Role: CAT (Catalyst use), USES (Uses) (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst); 4003-94-5; 39228-29-0; 114164-92-0; 130489-97-3; 433288-93-8; 433288-95-0; 433288-98-3; 433289-00-0; 433289-01-1; 433289-02-2; 433289-03-3 Role: RCT (Reactant), RACT (Reactant or reagent) (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst); 433289-12-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst); 1664-65-9P; 14310-29-3P; 20716-26-1P; 433289-04-4P; 433289-05-5P; 433289-06-6P; 433289-07-7P; 433289-08-8P; 433289-09-9P; 433289-10-2P; 433289-11-3P Role: SPN (Synthetic preparation), PREP (Preparation) (hydrogenation of olefins in the presence of an arom. nitro function catalyzed by Wilkinson's catalyst)

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LSPN  
Available on Infoscience
November 25, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/58499