Microwave-Assisted Intramolecular Suzuki-Miyaura Reaction to Macrocycle, a Concise Asymmetric Total Synthesis of Biphenomycin B

A concise and efficient total synthesis of biphenomycin B (I) was accomplished featuring a key microwave-assisted intramol. Suzuki-Miyaura reaction for formation of the 15-membered meta,meta-cyclophane 20. [on SciFinder (R)]


Published in:
Organic Letters, 7, 14, 2981-2984
Year:
2005
Keywords:
Note:
CAN 143:173123
34-3
Amino Acids, Peptides, and Proteins
Institut de Chimie des Substances Naturelles,CNRS,Gif-sur-Yvette,Fr.
Journal
1523-7060
written in English.
161053-46-9; 200132-54-3; 657408-07-6 Role: CAT (Catalyst use), USES (Uses) (microwave-assisted intramol. Suzuki-Miyaura reaction to macrocycle, a concise asym. total synthesis of biphenomycin B); 81477-94-3; 109838-85-9; 630400-87-2; 630400-88-3; 861099-84-5; 861099-93-6 Role: RCT (Reactant), RACT (Reactant or reagent) (microwave-assisted intramol. Suzuki-Miyaura reaction to macrocycle, a concise asym. total synthesis of biphenomycin B); 861099-80-1P; 861099-81-2P; 861099-82-3P; 861099-85-6P; 861099-86-7P; 861099-87-8P; 861099-90-3P; 861099-91-4P; 861099-92-5P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (microwave-assisted intramol. Suzuki-Miyaura reaction to macrocycle, a concise asym. total synthesis of biphenomycin B); 73183-34-3P; 100217-74-1P; 636594-77-9P; 861099-83-4P; 861099-88-9P; 861099-89-0P Role: SPN (Synthetic preparation), PREP (Preparation) (microwave-assisted intramol. Suzuki-Miyaura reaction to macrocycle, a concise asym. total synthesis of biphenomycin B)
Laboratories:




 Record created 2010-11-25, last modified 2018-03-17


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