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2009
Catalytic Formal Homo-Nazarov Cyclization
research article
The first catalytic method for the cyclization of vinyl-cyclopropyl ketones (formal homo-Nazarov reaction) is reported. Starting from activated cyclopropanes, heterocyclic and carbocyclic compounds were obtained under mild conditions using Brønsted acid catalysts. Preliminary investigation of the reaction mechanism indicated a stepwise process.
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OL2009-1023GreenAccess.pdf
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openaccess
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2.6 MB
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Adobe PDF
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e587b84d000797e8d643dedf16c41c89