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research article

Catalytic Formal Homo-Nazarov Cyclization

De Simone, Filippo  
•
Andrès, Julien
•
Torosantucci, Riccardo
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2009
Organic Letters

The first catalytic method for the cyclization of vinyl-cyclopropyl ketones (formal homo-Nazarov reaction) is reported. Starting from activated cyclopropanes, heterocyclic and carbocyclic compounds were obtained under mild conditions using Brønsted acid catalysts. Preliminary investigation of the reaction mechanism indicated a stepwise process.

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Type
research article
DOI
10.1021/ol802970g
Web of Science ID

WOS:000263299000060

Author(s)
De Simone, Filippo  
Andrès, Julien
Torosantucci, Riccardo
Waser, Jérôme  
Date Issued

2009

Publisher

American Chemical Society

Published in
Organic Letters
Volume

11

Issue

4

Start page

1023

End page

1026

Subjects

Aryl Cyclopropyl Ketones

•

Acid

•

Route

•

Acylcyclopropanes

•

Mechanism

•

Aldehydes

•

Scope

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LCSO  
Available on Infoscience
February 18, 2009
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/35478
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