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  4. Raman study of the Verwey transition in magnetite at high-pressure and low-temperature: Effect of Al doping
 
research article

Raman study of the Verwey transition in magnetite at high-pressure and low-temperature: Effect of Al doping

Gasparov, L.
•
Shirshikova, Z.
•
Pekarek, T. M.
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2012
Journal Of Applied Physics

We employed Raman spectroscopy to investigate how the hydrostatic pressure affects the temperature of the Verwey transition in pure (Fe3O4) and Al-doped (Fe2.8Al0.2O4) magnetite. In both samples, pressure suppresses the transition. The Al-doped sample displays no transition above 8 GPa. We do not observe such discontinuity in a pure magnetite, which suggests that the discontinuity is doping driven. Our Clausius-Clapeyron formula based analysis of the pressure-transition temperature dependence is in excellent agreement with our data in pure magnetite. The Al doping leads to a smaller entropy change and larger volume expansion consistent with partial charge ordering at the transition. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4747834]

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Type
research article
DOI
10.1063/1.4747834
Web of Science ID

WOS:000308410100024

Author(s)
Gasparov, L.
Shirshikova, Z.
Pekarek, T. M.
Blackburn, J.
Struzhkin, V.
Gavriliuk, A.
Rueckamp, R.
Berger, H.  
Date Issued

2012

Publisher

Amer Inst Physics

Published in
Journal Of Applied Physics
Volume

112

Issue

4

Article Number

043510

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSE  
Available on Infoscience
February 27, 2013
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/89665
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