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research article

Direct mapping of the solid-liquid adhesion energy with subnanometre resolution

Voitchovsky, Kislon  
•
Kuna, Jeffrey J.
•
Contera, Sonia Antoranz
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2010
Nature Nanotechnology

Solid-liquid interfaces play a fundamental role in surface electrochemistry(1), catalysis(2), wetting(3), self-assembly(4) and biomolecular functions(5). The interfacial energy determines many of the properties of such interfaces, including the arrangement of the liquid molecules at the surface of the solid. Diffraction techniques are often used to investigate the structure of solid-liquid interfaces(6), but measurements of irregular or inhomogeneous interfaces remain challenging. Here, we report atomic-and molecular-resolution images of various organic and inorganic samples in liquids, obtained with a commercial atomic force microscope operated dynamically with small-amplitude modulation. This approach uses the structured liquid layers close to the solid to enhance lateral resolution. We propose a model to explain the mechanism dominating the image formation, and show that the energy dissipated during this process is related to the interfacial energy through a readily achievable calibration curve. Our topographic images and interfacial energy maps could provide insights into important interfaces.

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Type
research article
DOI
10.1038/NNANO.2010.67
Web of Science ID

WOS:000279106500011

Author(s)
Voitchovsky, Kislon  
Kuna, Jeffrey J.
Contera, Sonia Antoranz
Tosatti, Erio
Stellacci, Francesco  
Date Issued

2010

Published in
Nature Nanotechnology
Volume

5

Issue

6

Start page

401

End page

405

Subjects

Atomic-Force Microscopy

•

Interfaces

•

Surface

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
SUNMIL  
Available on Infoscience
December 16, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/75394
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