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research article
A Synthetic Entry into the Taiwaniaquinoids Based on a Biogenetic Hypothesis: Total Synthesis of (-)-Taiwaniaquinone H
(Chemical Equation Presented) Less carbon: Following a biogenetic proposal, the unusual 6-5-6 carbon skeleton of C19 taiwaniaquinoids was obtained by an intramolecular benzilic acid rearrangement from a C20 precur-sor. A protecting-group-free total synthesis then allowed for the preparation of (-)-taiwaniaquinone H (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Type
research article
Web of Science ID
WOS:000280431900005
Authors
Publication date
2010
Published in
Volume
16
Start page
7692
End page
7695
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
December 16, 2011