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research article

Size effect in ferroelectrics: Competition between geometrical and crystalline symmetries

Wang, Jin  
•
Tagantsev, Alexander  
•
Setter, Nava  
2011
Physical Review B

Size effect in ferroelectrics is treated as a competition between the geometrical symmetry of the ferroelectric sample and its crystalline symmetry. Polarization rotation is shown to be a clear finite size effect that results from this competition, which can be induced by all types of driving forces that are coupled with the sample geometry, such as electrical, mechanical and/or thermal. The concept is illustrated with the Landau theory analysis of the polarization state of a cylindrical nanowire of the prototypical ferroelectric PbTiO3 having its axis parallel to [111] direction. It is shown that this system exhibits a polarization rotation driven by variations of the wire radius or/and temperature. An additional feature of the system is the occurrence of the rhombohedral phase which does not exist in bulk PbTiO3.

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Type
research article
DOI
10.1103/PhysRevB.83.014104
Web of Science ID

WOS:000286740200004

Author(s)
Wang, Jin  
Tagantsev, Alexander  
Setter, Nava  
Date Issued

2011

Published in
Physical Review B
Volume

83

Issue

1

Article Number

014104

Subjects

Phase-Transitions

•

Ultrathin Films

•

States

•

Nanowires

•

Oxide

Editorial or Peer reviewed

NON-REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
August 11, 2011
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/69986
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