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research article

Surface enhanced Raman scattering of carbon nanotubes decorated by individual fluorescent gold particles

Scolari, Matteo
•
Mews, Alf
•
Fu, Nan
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2008
Journal of Physical Chemistry C

Confocal optical microscopy was employed to study the effect of surface-enhanced Raman scattering on individual single-walled carbon nanotubes covered with isolated gold particles. The gold particles with diameters between 10 and 120 nm were deposited in low densities on the tubes' sidewalls by an electrochemical method. In the spectra, Raman peaks associated with the nanotubes were found to be superimposed on a broad luminescence background originating from the metal particles. With increasing particle size, both the luminescence intensity as well as the Raman enhancement increased at ion er wavelengths. This finding is consistent with a size-dependent broadening of the gold plasmon frequency and a corresponding extension of the energetic range for local field enhancement on the particle surface. In addition, wavelength-dependent experiments revealed a maximum Raman intensity when both nanotube and metal particle were in optical resonance.

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Type
research article
DOI
10.1021/jp076190i
Web of Science ID

WOS:000252287300012

Author(s)
Scolari, Matteo
Mews, Alf
Fu, Nan
Myalitsin, Anton
Assmus, Tilman
Balasubramanian, Kannan
Burghard, Marko  
Kern, K.  
Date Issued

2008

Published in
Journal of Physical Chemistry C
Volume

112

Start page

391

End page

396

Subjects

Single

•

Nanoparticles

•

Metal

•

Nanorods

•

Photoluminescence

•

Conductivity

•

Spectroscopy

•

Microscopy

•

Bundles

•

Silver

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSEN  
Available on Infoscience
November 30, 2010
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/61656
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