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research article

Piezoelectric properties of Li- and Ta-modified (K0.5Na0.5)NbO3 ceramics

Hollenstein, E.  
•
Davis, M.  
•
Damjanovic, D.  
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2005
Applied Physics Letters

Lead-free, potassium sodium niobate piezoelectric ceramics substituted with lithium (K0.5-x/2,Na0.5-x/2,Li-x)NbO3 or lithium and tantalum (K0.5-x/2,Na0.5-x/2,Li-x)(Nb1-y,Ta-y)O-3 have been synthesized by traditional solid state sintering. The compositions chosen are among those recently reported to show high piezoelectric properties [Y. Saito, H. Takao, T. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, and M. Nakamura, Nature (London) 42, 84 (2004); Y. Guo, K. Kakimoto, and H. Ohsato, Appl. Phys. Lett. 85, 4121 (2004); Mater. Lett. 59, 241 (2005)]. We show that high densities and piezoelectric properties can be obtained for all compositions by pressureless sintering in air, without cold isostatic pressing, and without any sintering aid or special powder treatment. Resonance and converse piezoelectric (strain-field) measurements show a thickness coupling coefficient k(t) of 53% and converse piezoelectric coefficient d(33) around 200 pm/V for the Li-substituted ceramics, and a k(t) of 52% and d(33) over 300 pm/V for the Li- and Ta-modified samples. The unipolar strain-field hysteresis is small and comparable to that measured under similar conditions in hard Pb(Zr,Ti)O-3. A peak of piezoelectric properties can be noted close to the morphotropic phase boundary. These ceramics look very promising as possible, practicable, lead-free replacements for lead zirconate titanate.(C) 2005 American Institute of Physics.

  • Details
  • Metrics
Type
research article
DOI
10.1063/1.2123387
Web of Science ID

WOS:000232886400056

Author(s)
Hollenstein, E.  
Davis, M.  
Damjanovic, D.  
Setter, N.  
Date Issued

2005

Published in
Applied Physics Letters
Volume

87

Issue

18

Article Number

182905

Subjects

behavior

Note

Hollenstein, E Ecole Polytech Fed Lausanne, Ceram Lab, Lausanne, Switzerland Ecole Polytech Fed Lausanne, Ceram Lab, Lausanne, Switzerland

978PV

Cited References Count:14

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
August 21, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/233563
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