Repository logo

Infoscience

  • English
  • French
Log In
Logo EPFL, École polytechnique fédérale de Lausanne

Infoscience

  • English
  • French
Log In
  1. Home
  2. Academic and Research Output
  3. Journal articles
  4. Use of ferroelectric hysteresis parameters for evaluation of niobium effects in lead zirconate titanate thin films
 
research article

Use of ferroelectric hysteresis parameters for evaluation of niobium effects in lead zirconate titanate thin films

Klissurska, R. D.
•
Tagantsev, A. K.  
•
Brooks, K. G.
Show more
1997
Journal of the American Ceramic Society

The effects of niobium doping on the hysteresis parameters of sol-gel Pb-1.1-x/2(Zr0.53Ti0.47)(1-x)NbxO3 (0 < x < 0.05) have been reported fbr two sets of films with analogous grain size and degree of (111) texture but with different surface microstructures. For both sets, a strong continuous decay of the remnant and maximum polarizations and slope of the hysteresis loop at the coercive field was observed with increasing niobium concentration. The held dependence of the remnant polarization for any given niobium-doped him was identical to the functional field dependence of the undoped reference him, if multiplied by a niobium-concentration-dependent constant. Although the maximum and remnant polarizations decayed as the dopant level increased, their difference remained the same value as that of the undoped him at any given field. The width of the loop (at zero polarization) was insensitive to the niobium concentration at any given held, A linear increase in coercive held asymmetry (up to 40 kV/cm) was observed with niobium addition, yet was field independent and, thus, electrostatic in origin. Niobium governed switching through a reduction of the number of switching domains, without changing the total lattice polarization response. Microstructure-related effects on switching, such as decreased volume fraction of ferroelectric material or field-screening effects due to the presence of a pyrochlore second phase, were eliminated as the origin of the hysteresis changes. This paper has demonstrated how hysteresis features and their field dependencies can be used to separate the effects of niobium-induced microstructural changes from niobium lattice doping influences on the hysteresis loops.

  • Details
  • Metrics
Type
research article
DOI
10.1111/j.1151-2916.1997.tb02835.x
Web of Science ID

WOS:A1997WK08500009

Author(s)
Klissurska, R. D.
Tagantsev, A. K.  
Brooks, K. G.
Setter, N.  
Date Issued

1997

Published in
Journal of the American Ceramic Society
Volume

80

Issue

2

Start page

336

End page

342

Subjects

memories

•

pb(zr

Note

Klissurska, RD Ecole Polytech Fed Lausanne,Lab Ceram,Ch-1015 Lausanne,Switzerland

Wk085

Cited References Count:23

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
August 21, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/233309
Logo EPFL, École polytechnique fédérale de Lausanne
  • Contact
  • infoscience@epfl.ch

  • Follow us on Facebook
  • Follow us on Instagram
  • Follow us on LinkedIn
  • Follow us on X
  • Follow us on Youtube
AccessibilityLegal noticePrivacy policyCookie settingsEnd User AgreementGet helpFeedback

Infoscience is a service managed and provided by the Library and IT Services of EPFL. © EPFL, tous droits réservés