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  4. Role of Defects in the Ferroelectric Relaxer Lead Scandium Tantalate
 
research article

Role of Defects in the Ferroelectric Relaxer Lead Scandium Tantalate

CHU, F.
•
Reaney, I. M.
•
Setter, N.  
1995
Journal of the American Ceramic Society

Unlike Pb(Mg1/3Nb2/3)O-3 and similar ferroelectric relaxors which never truly become ferroelectric at zero-field, disordered Pb(Sc1/2Ta1/2)O-3 (PST) is a relaxer that spontaneously transforms into a ferroelectric phase. The control of the degree of order of the B-site cations in PST by appropriate heat treatment has been often used to demonstrate the influence of chemical disorder on the dielectric properties of ferroelectrics. Here it is shown that, in PST, disorder itself is not sufficient to prevent a macroscopic ferroelectric transition, and that disordered stoichiometric PST exhibits a strong dielectric relaxation, but upon cooling it spontaneously becomes a macroscopic ferroelectric. Lead deficiency in disordered Pb(Sc1/2Ta1/2)O-3 prevents this spontaneous ferroelectric transformation, and the material shows more usual relaxer properties.

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Type
research article
DOI
10.1111/j.1151-2916.1995.tb08915.x
Web of Science ID

WOS:A1995RJ68000036

Author(s)
CHU, F.
Reaney, I. M.
Setter, N.  
Date Issued

1995

Published in
Journal of the American Ceramic Society
Volume

78

Issue

7

Start page

1947

End page

1952

Subjects

diffuse phase-transitions

•

magnesium niobate

•

disorder

•

pb(sc0.5ta0.5)o3

Note

CHU, F Ecole Polytech Fed Lausanne,Mxc Ecublens,Ceram Lab,Ch-1015 Lausanne,Switzerland

Rj680

Cited References Count:17

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LC  
Available on Infoscience
August 21, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/233256
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