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research article

Divergent double chirp pulses for refocusing quadrupolar interactions

Fu, Riqiang
•
Ermakov, Vladimir L.
•
Bodenhausen, Geoffrey  
1996
Solid State Nuclear Magnetic Resonance

To excite and refocus single quantum coherences in a three-level system with a quadrupolar interaction, it is possible to use frequency-modulated pulses with two diverging frequency components that are swept simultaneously through the two single-quantum transitions. This is achieved by time-dependent amplitude-modulation of the carrier frequency, so as to generate two sidebands with frequencies that are diverging (or converging) sym. with respect to the carrier frequency. Simulations and expts. show that such modulated pulses can be used to refocus single quantum coherences to form quadrupole echoes, using much weaker RF amplitudes than in conventional echo sequences. To visualize the evolution of the coherences in a three-level system, a graphical representation of the d. operator components is proposed. [on SciFinder (R)]

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Type
research article
DOI
10.1016/0926-2040(96)01231-3
Author(s)
Fu, Riqiang
Ermakov, Vladimir L.
Bodenhausen, Geoffrey  
Date Issued

1996

Published in
Solid State Nuclear Magnetic Resonance
Volume

7

Issue

1

Start page

1

End page

10

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LRMB  
Available on Infoscience
February 22, 2006
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/225604
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