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research article
Electrochemical perfluorination of organic acids. Mechanism
Electrochem. perfluorination of octanesulfonyl fluoride [40630-63-5] and octanoyl fluoride [592-94-9] to their fluoro compds. was studied over a wide range of exptl. conditions. Significant improvement of the reported yield of perfluoro-product was achieved with electrolysis at high potential. The results are explained in terms of a model involving simultaneous adsorption of the reactant and of F on a NiF2 surface. [on SciFinder (R)]
Type
research article
Authors
Publication date
1974
Published in
Volume
4
Issue
4
Start page
289
End page
92
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
February 22, 2006
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