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  4. Electrochemical sensors modified with iron oxide nanoparticles/ nanocomposites for voltammetric detection of Pb (II) in water: A review
 
review article

Electrochemical sensors modified with iron oxide nanoparticles/ nanocomposites for voltammetric detection of Pb (II) in water: A review

Jjagwe, Joseph
•
Olupot, Peter Wilberforce
•
Kulabako, Robinah
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April 30, 2024
Heliyon

Permissible limits of Pb 2+ in drinking water are being reduced from 10 mu gL -1 to 5 mu gL -1 , which calls for rapid, and highly reliable detection techniques. Electrochemical sensors have garnered attention in detection of heavy metal ions in environmental samples due to their ease of operation, low cost, and rapid detection responses. Selectivity, sensitivity and detection capabilities of these sensors, can be enhanced by modifying their working electrodes (WEs) with iron oxide nanoparticles (IONPs) and/or their composites. Therefore, this review is an in-depth analysis of the deployment of IONPs/nanocomposites in modification of electrochemical sensors for detection of Pb 2+ in drinking water over the past decade. From the analyzed studies (n = 23), the optimal solution pH, deposition potential, and deposition time ranged between 3 and 5.6, -0.7 to -1.4 V vs Ag/AgCl, and 100 - 400 s, respectively. Majority of the studies employed square wave anodic stripping voltammetry (n = 16), in 0.1 M acetate buffer solution (n = 19) for detection of Pb 2+ . Limits of detection obtained (2.5 x 10 -9 - 4.5 mu g/L) were below the permissible levels which indicated good sensitivities of the modified electrodes. Despite the great performance of these modified electrodes, the primary source of IONPs has always been commercial iron -based salts in addition to the use of so many materials as modifying agents of these IONPs. This may limit reproducibility and sustainability of the WEs due to lengthy and costly preparation protocols. Steel and/or iron industrial wastes can be alternatively employed in generation of IONPs for modification of electrochemical sensors. Additionally, biomass -based activated carbons enriched with surface functional groups are also used in modification of bare IONPs, and subsequently bare electrodes. However, these two areas still need to be fully explored.

  • Details
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Type
review article
DOI
10.1016/j.heliyon.2024.e29743
Web of Science ID

WOS:001233574500001

Author(s)
Jjagwe, Joseph
Olupot, Peter Wilberforce
Kulabako, Robinah
Carrara, Sandro  
Date Issued

2024-04-30

Publisher

Cell Press

Published in
Heliyon
Volume

10

Issue

8

Article Number

e29743

Subjects

Metal Oxide

•

Voltammetry

•

Functionalization

•

Working Electrode

•

Lead

•

Drinking Water

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSI1  
FunderGrant Number

Africa program under the UM6P - EPFL Excellence in Africa Initiative

Available on Infoscience
June 19, 2024
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/208661
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