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research article
Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer
March 10, 2022
The reaction of a terminal Mo(II) nitride with a U(III) complex yields an heterodimetallic U-Mo nitride which is the first example of a transition metal-capped uranium nitride. The nitride is triply bonded to U(V) and singly bonded to Mo(0) and supports a U-Mo interaction. This compound shows reactivity toward CO oxidation.
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D2CC00473A.pdf
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