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  4. Liquid metal infiltration of silicon based alloys into porous carbonaceous materials. Part II: Experimental verification of modelling approaches by infiltration of Si-Zr alloy into idealized microchannels
 
research article

Liquid metal infiltration of silicon based alloys into porous carbonaceous materials. Part II: Experimental verification of modelling approaches by infiltration of Si-Zr alloy into idealized microchannels

Naikade, Manoj
•
Hain, Caroline
•
Kastelik, Kaja
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May 1, 2022
Journal Of The European Ceramic Society

In this work, the mechanisms leading to the pore closure in reactive melt infiltration (RMI) of carbon by pure silicon and a near eutectic Si-8 at-pct Zr alloy at 1500 and 1700 degrees C under vacuum were studied. Various geometrical configurations of microchannels were fabricated via laser ablation of glassy carbon plates. The micron size capillary channels allowed simplifying the complicated porosity distribution in the infiltration of powder or fibres based porous preform while keeping the physical dimensions in the range of where the physical phenomenon of pore closure takes place. The extent of infiltration was analysed by means of X-ray radiography. For RMI of pure Si, the widely accepted decrease in capillary radius by the formation of a solid state SiC layer by the reaction of liquid Si and C was observed, but did not lead to closure and it is hence not the infiltration limiting step in channels as small as 10 mu m. However, in the case of the Si-Zr alloy infiltration, another mechanism of pore closure was observed, namely the precipitation of zirconium silicides at the infiltration front, due to Zr enrichment in the alloy by the continuous consumption of Si for the formation of SiC.

  • Details
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Type
research article
DOI
10.1016/j.jeurceramsoc.2022.01.004
Web of Science ID

WOS:000751865600006

Author(s)
Naikade, Manoj
Hain, Caroline
Kastelik, Kaja
Bronnimann, Rolf
Bianchi, Giovanni
Ortona, Alberto
Graule, Thomas
Weber, Ludger  
Date Issued

2022-05-01

Publisher

ELSEVIER SCI LTD

Published in
Journal Of The European Ceramic Society
Volume

42

Issue

5

Start page

1984

End page

1994

Subjects

Materials Science, Ceramics

•

Materials Science

•

lsi

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rmi

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sic composites

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si-zr alloy infiltration

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microchannel

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capillary infiltration

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reactive infiltration

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melt infiltration

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hf alloy

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composites

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carbide

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fabrication

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graphite

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wettability

•

dynamics

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LMM  
Available on Infoscience
February 28, 2022
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/185822
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