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research article
Nitrous oxide as a diazo transfer reagent: the synthesis of triazolopyridines
Nitrous oxide is a potential diazo transfer reagent, but its applications in organic chemistry are scarce. Here, we show that triazolopyridines and triazoloquinolines are formed in the reactions of metallated 2-alkylpyridines or 2-alkylquinolines with N2O. The reactions can be performed under mild conditions and give synthetically interesting triazoles in moderate to good yields.
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Name
Accepted Manuscript Not Edited.pdf
Type
postprint
Access type
openaccess
License Condition
copyright
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503.49 KB
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Adobe PDF
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