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  4. Interfacial passivation of wide-bandgap perovskite solar cells and tandem solar cells
 
research article

Interfacial passivation of wide-bandgap perovskite solar cells and tandem solar cells

Xia, Rui
•
Xu, Yibo
•
Chen, Bingbing
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August 19, 2021
Journal of Materials Chemistry A

Perovskite/silicon tandem solar cells offer the potential to surpass the power conversion efficiency (PCE) of single-junction solar devices beyond the Shockley-Queisser limit at relatively low costs. However, obtaining wide-bandgap materials that provide improved efficiency and appropriate stability is very challenging due to their increased trap density and frequent phase instability under light. Here we report stable wide-bandgap (similar to 1.7 eV) perovskite devices achieving efficiencies of 19.67%, and open-circuit voltages (V-oc) above 1.2 V via a suitable combination of vacuum-assisted solution processing (VASP) and interfacial passivation. Such a facile approach can be translated to multiple perovskite compositions, enabling the fabrication of efficient and stable wide-bandgap cells and their integration into monolithic silicon tandem structures with 24.01% PCE, one of the highest efficiencies for n-i-p tandem devices reported so far.

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Type
research article
DOI
10.1039/d1ta04330g
Web of Science ID

WOS:000696283700001

Author(s)
Xia, Rui
Xu, Yibo
Chen, Bingbing
Kanda, Hiroyuki  
Franckevicius, Marius
Gegevicius, Rokas
Wang, Shubo
Chen, Yifeng
Chen, Daming
Ding, Jianning
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Date Issued

2021-08-19

Publisher

Royal Society of Chemistry

Published in
Journal of Materials Chemistry A
Volume

9

Issue

38

Start page

21939

End page

21947

Subjects

Chemistry, Physical

•

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Chemistry

•

Energy & Fuels

•

Materials Science

•

gap perovskites

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GMF  
LCOM  
Available on Infoscience
September 25, 2021
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/181719
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