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review article

New Strategies for Defect Passivation in High-Efficiency Perovskite Solar Cells

Akin, Seckin  
•
Arora, Neha
•
Zakeeruddin, Shaik Mohammed  
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November 19, 2019
Advanced Energy Materials

Lead halide perovskite solar cells now show excellent efficiencies and encouraging levels of stability. Further improvements in performance require better control of the trap states which are considered to be associated with vacancies and defects at crystallite surfaces. Herein, a reflection on the ways in which these traps can be mitigated is presented by improving the quality of the perovskite layer and interfaces in fully assembled device configurations. In this review, the most recent design strategies reported in the literature, which have been explored to tune grain orientation, to passivate defects, and to improve charge-carrier lifetimes, are presented. Specifically, the advances made with single-cation, mixed-cation and/or mixed-halide, and 3D/2D bilayer-based light absorbers are discussed. The interfacial, compositional, and band alignment engineering along with their consequent effects on the open-circuit voltage, power conversion efficiency, and stability are a particular focus.

  • Details
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Type
review article
DOI
10.1002/aenm.201903090
Web of Science ID

WOS:000497158800001

Author(s)
Akin, Seckin  
Arora, Neha
Zakeeruddin, Shaik Mohammed  
Graetzel, Michael  
Friend, Richard H.
Dar, M. Ibrahim
Date Issued

2019-11-19

Publisher

WILEY-V C H VERLAG GMBH

Published in
Advanced Energy Materials
Article Number

1903090

Subjects

Chemistry, Physical

•

Energy & Fuels

•

Materials Science, Multidisciplinary

•

Physics, Applied

•

Physics, Condensed Matter

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Chemistry

•

Energy & Fuels

•

Materials Science

•

Physics

•

2d-3d

•

defects

•

efficiency

•

engineering

•

mixed-cation-halide

•

passivation

•

perovskite solar cells

•

stability

•

hole-transporting material

•

metal halide perovskites

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open-circuit voltage

•

assisted crystallization

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interfacial layer

•

planar

•

performance

•

stability

•

cation

•

iodide

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LPI  
Available on Infoscience
November 29, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/163461
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