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  4. A Scalable Methylamine Gas Healing Strategy for High-Efficiency Inorganic Perovskite Solar Cells
 
research article

A Scalable Methylamine Gas Healing Strategy for High-Efficiency Inorganic Perovskite Solar Cells

Shao, Zhipeng
•
Wang, Zaiwei  
•
Li, Zhipeng
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April 16, 2019
Angewandte Chemie International Edition

An easy and scalable methylamine (MA) gas healing method was realized for inorganic cesium-based perovskite (CsPbX3) layers by incorporating a certain amount of MAX (X=I or Br) initiators into the raw film. It was found that the excess MAX accelerated the absorption of the MA gas into the CsPbX3 film and quickly turned it into a liquid intermediate phase. Through the healing process, a highly uniform and highly crystalline CsPbX3 film with enhanced photovoltaic performance was obtained. Moreover, the chemical interactions between a series of halides and MA gas molecules were studied, and the results could offer guidance in further optimizations of the healing strategy.

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Type
research article
DOI
10.1002/anie.201814024
Web of Science ID

WOS:000466593400014

Author(s)
Shao, Zhipeng
Wang, Zaiwei  
Li, Zhipeng
Fan, Yingping
Meng, Hongguang
Liu, Ranran
Wang, Yan
Hagfeldt, Anders  
Cui, Guanglei
Pang, Shuping
Date Issued

2019-04-16

Publisher

Wiley-VCH Verlag GmbH

Published in
Angewandte Chemie International Edition
Volume

58

Issue

17

Start page

5587

End page

5591

Subjects

Chemistry, Multidisciplinary

•

Chemistry

•

defect healing

•

inorganic perovskites

•

methylamine

•

solar cells

•

thin films

•

evolution

Editorial or Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
LSPM  
Available on Infoscience
June 18, 2019
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/157684
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