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research article
The influence of external electric fields on charge reorganization energy in organic semiconductors
February 25, 2019
Charge reorganization energies (k) of inter-ring carbon-carbon (IRCC) bond connected conjugated polycyclics are shown to exhibit an electric-field-driven anisotropic character. An external electric field parallel to the IRCC linker(s) reduces k while the field vertical to the molecular plane does the opposite. This anisotropic character can be modulated by introducing inter-ring noncovalent locks into appropriate sites.
Type
research article
Web of Science ID
WOS:000459022300030
Authors
Publication date
2019-02-25
Publisher
Published in
Volume
55
Issue
16
Start page
2384
End page
2387
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
June 18, 2019
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