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  4. Migration of cations induces reversible performance losses over day​/night cycling in perovskite solar cells
 
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research article

Migration of cations induces reversible performance losses over day​/night cycling in perovskite solar cells

Domanski, Konrad  
•
Roose, Bart
•
Matsui, Taisuke
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2017
Energy & Environmental Science

Perovskites have been demonstrated in solar cells with a power conversion efficiency of well above 20​%, which makes them one of the strongest contenders for next generation photovoltaics. While there are no concerns about their efficiency, very little is known about their stability under illumination and load. Ionic defects and their migration in the perovskite crystal lattice are some of the most alarming sources of degrdn., which can potentially prevent the commercialization of perovskite solar cells (PSCs)​. In this work, we provide direct evidence of elec. field-​induced ionic defect migration and we isolate their effect on the long-​term performance of state-​of-​the-​art devices. Supported by modeling, we demonstrate that ionic defects, migrating on timescales significantly longer (above 103 s) than what has so far been explored (from 10-​1 to 102 s)​, abate the initial efficiency by 10-​15​% after several hours of operation at the max. power point. Though these losses are not negligible, we prove that the initial efficiency is fully recovered when leaving the device in the dark for a comparable amt. of time. We verified this behavior over several cycles resembling day​/night phases, thus probing the stability of PSCs under native working conditions. This unusual behavior reveals that research and industrial stds. currently in use to assess the performance and the stability of solar cells need to be adjusted for PSCs. Our work paves the way for much needed new testing protocols and figures of merit specifically designed for PSCs.

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Type
research article
DOI
10.1039/C6EE03352K
Web of Science ID

WOS:000395679100019

Author(s)
Domanski, Konrad  
•
Roose, Bart
•
Matsui, Taisuke
•
Saliba, Michael  
•
Turren-Cruz, Silver-Hamill
•
Correa-Baena, Juan-Pablo
•
Carmona, Cristina Roldan
•
Richardson, Giles
•
Foster, Jamie M.
•
De Angelis, Filippo
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Date Issued

2017

Publisher

Royal Soc Chemistry

Published in
Energy & Environmental Science
Volume

10

Issue

2

Start page

604

End page

613

Peer reviewed

REVIEWED

Written at

EPFL

EPFL units
GMF  
LPI  
Available on Infoscience
March 11, 2017
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/135197
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