Chiral expression of adsorbed (MP) 5-amino[6] helicenes: from random structures to dense racemic crystals by surface alloying
The chiral expression of a molecule on a surface is driven from a random solid solution on Cu(100) to a racemic crystal on a Sn/Cu(100) alloy. Density functional theory simulations reveal how the growth of the racemate is influenced by the underlying surface.
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Fuhr, J. D., Van Der Meijden, M. W., Cristina, L. J., Rodriguez, L. M., Kellogg, R. M., Gayone, J. E., Ascolani, H., & Lingenfelder, M. (2017). Chiral expression of adsorbed (MP) 5-amino[6] helicenes: from random structures to dense racemic crystals by surface alloying. Chemical Communications (ChemComm), 53(1), 130–133. https://doi.org/10.1039/c6cc06785a
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WOS:000391607100016
2017
53
1
130
133
REVIEWED
EPFL