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research article

Mild reactive stripping of coordinating ligands from nanocrystal surfaces using Meerwein's salt

Rosen, Evelyn L.
•
Buonsanti, Raffaella  
•
Llordes, Anna
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2012
Angewandte Chemie International Edition

Native coordinating ligands acquired during the chem. synthesis of colloidal nanocrystals are optimized primarily for their ability to exert control over nanocrystal size, compn., morphol., and dispersibility, and not necessarily for their final application. In general, they are hydrophobic and highly insulating, and constitute a significant barrier for charge or ion transport in devices configured therefrom. Bare nanocrystal surfaces, while desirable for many applications are difficult to obtain reliably. This study relates to a universal reagent for producing stable dispersions or thin films of ligand-stripped nanocrystals with retention of their phys. properties, showing that this can be uniquely achieved by using Meerwein's (Et3OBF4) and other trialkyl oxonium salts to investigate reactive ligand stripping of oleate-passivated lead selenide nanocrystals (PbSe-OA).

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Type
research article
DOI
10.1002/anie.201105996
Author(s)
Rosen, Evelyn L.
Buonsanti, Raffaella  
Llordes, Anna
Sawvel, April M.
Milliron, Delia J.
Helms, Brett A.
Date Issued

2012

Publisher

Wiley-VCH Verlag GmbH

Published in
Angewandte Chemie International Edition
Volume

51

Start page

684

End page

689

Subjects

stripping ligands nanocrystal surface Meerwein's salt

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
LNCE  
Available on Infoscience
December 22, 2016
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/132223
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