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research article
Chiral N-Heterocyclic Carbene Ligand Enabled Nickel(0)-Catalyzed Enantioselective Three-Component Couplings as Direct Access to Silylated Indanols
2016
An enantioselective nickel(0)-catalyzed reductive three-component coupling between aromatic aldehydes, norbornenes, and silanes affords directly silyl-protected indanol derivatives. A new bulky chiral C-2-symmetric NHC (NHC = N-heterocyclic carbene) ligand basing on the 1,2-di(napthalen-1-yl)ethylene diamine backbone allows accessing the annulated products as single diastereoisomers in high enantioselectivity.
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Type
research article
Web of Science ID
WOS:000379455300051
Authors
Publication date
2016
Publisher
Published in
Volume
18
Issue
13
Start page
3242
End page
3245
Peer reviewed
REVIEWED
EPFL units
Available on Infoscience
October 18, 2016