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research article

Kinetics of laser-assisted carbon nanotube growth

Van De Burgt, Y.
•
Bellouard, Y.  
•
Mandamparambil, R.
2014
Physical Chemistry Chemical Physics

Laser-assisted chemical vapour deposition (CVD) growth is an attractive mask-less process for growing locally aligned carbon nanotubes (CNTs) in selected places on temperature sensitive substrates. The nature of the localized process results in fast carbon nanotube growth with high experimental throughput. Here, we report on detailed investigation of growth kinetics related to physical and chemical process characteristics. Specifically, the growth kinetics is investigated by monitoring the dynamical changes of reflected laser beam intensity during growth. Benefiting from the fast growth and high experimental throughput, we investigate a wide range of experimental conditions and propose several growth regimes. Rate-limiting steps are determined using rate equations linked to the proposed growth regimes, which are further characterized by Raman spectroscopy and Scanning Electron Microscopy (SEM), therefore directly linking growth regimes to the structural quality of the CNTs. Activation energies for the different regimes are found in the range of 0.3 – 0.8 eV.

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Type
research article
DOI
10.1039/c4cp00061g
Author(s)
Van De Burgt, Y.
Bellouard, Y.  
Mandamparambil, R.
Date Issued

2014

Published in
Physical Chemistry Chemical Physics
Volume

16

Issue

11

Start page

5162

End page

5173

Editorial or Peer reviewed

REVIEWED

Written at

OTHER

EPFL units
GALATEA  
Available on Infoscience
July 20, 2015
Use this identifier to reference this record
https://infoscience.epfl.ch/handle/20.500.14299/116410
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